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Aphthitalite

A valid IMA mineral species - grandfathered
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About AphthitaliteHide

Formula:
K3Na(SO4)2
Originally given as (K,Na)3Na(SO4)2.
Colour:
Colourless (rare), white, grey, bluish, greenish, reddish; colourless in transmitted light
Lustre:
Vitreous, Resinous
Hardness:
3
Specific Gravity:
2.656 - 2.71
Crystal System:
Trigonal
Name:
From the Greek άφθητος ("aphthitos"), "unalterable", and άλας ("halas"), "salt", in allusion to its stability in air.
Occurs in two widely diversified environments, both as an incrustation in volcanic fumaroles and as a constituent of oceanic and lacustrine salt deposits.

As shown by experiments of Africano et al. (2002), it may deposit from volcanic gas in high fO2 conditions during cooling from ca. 800 down to 400oC, together with thénardite.

Glaserite is a common synonym.
The K analogue of Natroaphthitalite.

Structurally related to bubnovaite. Both structurally and chemically related to belomarinaite.


Unique IdentifiersHide

Mindat ID:
280
Long-form identifier:
mindat:1:1:280:0

IMA Classification of AphthitaliteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
K3Na(S6+O4)2
First published:
1813

Classification of AphthitaliteHide

7.AC.35

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
A : Sulfates (selenates, etc.) without additional anions, without H2O
C : With medium-sized and large cations
28.2.2.1

28 : ANHYDROUS ACID AND NORMAL SULFATES
2 : A2XO4
25.1.7

25 : Sulphates
1 : Sulphates of the alkali metals and ammonium

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
AttIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of AphthitaliteHide

Vitreous, Resinous
Transparency:
Transparent, Translucent, Opaque
Colour:
Colourless (rare), white, grey, bluish, greenish, reddish; colourless in transmitted light
Streak:
White
Hardness:
Tenacity:
Brittle
Cleavage:
Imperfect/Fair
On {1010} fair; on {0001} poor.
Fracture:
Irregular/Uneven, Conchoidal
Density:
2.656 - 2.71 g/cm3 (Measured)    2.72 g/cm3 (Calculated)

Optical Data of AphthitaliteHide

Type:
Uniaxial (+)
RI values:
nω = 1.487 - 1.491 nε = 1.492 - 1.499
Max. Birefringence:
δ = 0.005 - 0.008
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Moderate (negative)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.

Chemistry of AphthitaliteHide

Mindat Formula:
K3Na(SO4)2

Originally given as (K,Na)3Na(SO4)2.
Element Weights:
Element% weight
O38.505 %
K35.286 %
S19.292 %
Na6.916 %

Calculated from ideal end-member formula.
O
K
S
Na

Crystallography of AphthitaliteHide

Crystal System:
Trigonal
Class (H-M):
3m(32/m) - Hexagonal Scalenohedral
Space Group:
P3m1
Setting:
P3m1
Cell Parameters:
a = 5.677 Å, c = 7.3331 Å
Ratio:
a:c = 1 : 1.292
Unit Cell V:
204.67 ų (Calculated from Unit Cell)
Z:
1
Morphology:
Crystals commonly thin to thick tabular with pronounced trigonal development. Distorted pseudo-orthorhombic forms. Bladed aggregates; mammilary; crusts; massive.
Twinning:
On {0001} or on {1120}, repeated. Twinned groups on {1120}, similar to aragonite twins.

Crystallographic forms of AphthitaliteHide

Crystal Atlas:
Image Loading
Image
Click on an icon to view
View 3D crystal model
Aphthitalite no.97 - {001} - Goldschmidt (1913-1926)
View 3D crystal model
Aphthitalite no.116 - {001} - Goldschmidt (1913-1926)
3d models and HTML5 code kindly provided by www.smorf.nl.

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Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0009708AphthitaliteOkada K, Ossaka J (1980) Structures of potassium sodium sulphate and tripotassium sodium disulphate Acta Crystallographica B36 919-921Image19800293
0017926AphthitaliteGossner B (1928) Ueber die Kristallstruktur von Glaserit und Kaliumsulfat. _cod_database_code 1011019 Neues Jahrbuch fur Mineralogie, Geologie und Palaeontologie. Beilage 57 89-11619280293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Loading XRD data...
Data Set:
Data courtesy of RRUFF project at University of Arizona, used with permission.
Powder Diffraction Data:
d-spacingIntensity
2.839 Å(100)
2.940 Å(75)
2.042 Å(45)
4.09 Å(30)
3.67 Å(20)
2.443 Å(16)
2.330 Å(14)
Comments:
Synthetic

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
25 : Evaporites (prebiotic)
Stage 7: Great Oxidation Event<2.4
45a : [Sulfates, arsenates, selenates, antimonates]
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere<0.6
49 : Oxic cellular biomineralization (see also #44)<0.54
52 : Guano- and urine-derived minerals<0.4

Type Occurrence of AphthitaliteHide

Synonyms of AphthitaliteHide

Other Language Names for AphthitaliteHide

Varieties of AphthitaliteHide

Ammonium-AphthitaliteAn ammonium-bearing variety of Aphthitalite. Occurs as fibrous crusts.

Originally reported from Guañape Island, La Libertad Department, Peru.
Copper- and Manganese-bearing AphthitaliteA Cu- and Mn-rich variety.

Relationship of Aphthitalite to other SpeciesHide

Common AssociatesHide

Associations Based on Photo Data:
7 photos of Aphthitalite associated with HaliteNaCl
2 photos of Aphthitalite associated with CalciojohilleriteNaCaMg3(AsO4)3
2 photos of Aphthitalite associated with HematiteFe2O3
2 photos of Aphthitalite associated with CassiteriteSnO2
2 photos of Aphthitalite associated with BadaloviteNa2Mg2Fe(AsO4)3
1 photo of Aphthitalite associated with AllantoinC4H6N4O3
1 photo of Aphthitalite associated with MolybdeniteMoS2
1 photo of Aphthitalite associated with LammeriteCu3(AsO4)2
1 photo of Aphthitalite associated with ParalammeriteCu3(AsO4)2
1 photo of Aphthitalite associated with KozyrevskiteCu4O(AsO4)2

Related Minerals - Strunz-mindat GroupingHide

7.AC.Aluminopyracmonite(NH4)3Al(SO4)3Trig. 3 : R3
7.AC.AmgaiteTl+32Te6+O6Trig. 32 : P321
7.AC.05VanthoffiteNa6Mg(SO4)4Mon. 2/m : P21/b
7.AC.08Pyracmonite(NH4)3Fe(SO4)3Trig. 3m : R3c
7.AC.10LangbeiniteK2Mg2(SO4)3Iso. 23 : P213
7.AC.10Efremovite(NH4)2Mg2(SO4)3Iso. 23 : P213
7.AC.10Ferroefremovite(NH4)2Fe2+2(SO4)3Iso. 23 : P213
7.AC.10ManganolangbeiniteK2Mn2(SO4)3Iso. 23 : P213
7.AC.15YavapaiiteKFe3+(S6+O4)2Mon. 2/m : B2/m
7.AC.15EldfelliteNaFe3+(SO4)2Mon. 2/m : B2/m
7.AC.20Sabieite(NH4)Fe3+(SO4)2Trig. 32 : P321
7.AC.20Godovikovite(NH4)Al(SO4)2Trig. 32 : P321
7.AC.20StekliteKAl(SO4)2Trig. 32 : P321
7.AC.35BelomarinaiteKNa(SO4)Trig. 3m : P31m
7.AC.35Natroaphthitalite KNa3(SO4)2Trig. 3m(32/m) : P3m1
7.AC.35Möhnite(NH4)K2Na(SO4)2Trig. 3m : P3m1
7.AC.40ItelmeniteNa4Mg3Cu3(SO4)8Orth. mmm(2/m2/m2/m) : Pbca
7.AC.45SaranchinaiteNa2Cu(SO4)2Mon. 2 : P21
7.AC.50MajzlaniteK2Na(ZnNa)Ca(SO4)4Mon. 2/m : B2/b
7.AC.60Philoxenite(K,Na,Pb)4(Na,Ca)2(Mg,Cu)3(Fe3+0.5Al0.5)(SO4)8Tric. 1 : P1
7.AC.75PetroviteNa12Cu2(SO4)8Mon. 2/m : P21/b

RadioactivityHide

Radioactivity:
Element % Content Activity (Bq/kg) Radiation Type
Uranium (U) 0.0000% 0 α, β, γ
Thorium (Th) 0.0000% 0 α, β, γ
Potassium (K) 35.2862% 10,939 β, γ

For comparison:

  • Banana: ~15 Bq per fruit
  • Granite: 1,000–3,000 Bq/kg
  • EU exemption limit: 10,000 Bq/kg

Note: Risk is shown relative to daily recommended maximum exposure to non-background radiation of 1000 µSv/year. Note that natural background radiation averages around 2400 µSv/year so in reality these risks are probably extremely overstated! With infrequent handling and safe storage natural radioactive minerals do not usually pose much risk.

Interactive Simulator:

Note: The mass selector refers to the mass of radioactive mineral present, not the full specimen, also be aware that the matrix may also be radioactive, possibly more radioactive than this mineral!

Activity:

DistanceDose rateRisk
1 cm
10 cm
1 m

The external dose rate (D) from a radioactive mineral is estimated by summing the gamma radiation contributions from its Uranium, Thorium, and Potassium content, disregarding daughter-product which may have a significant effect in some cases (eg 'pitchblende'). This involves multiplying the activity (A, in Bq) of each element by its specific gamma ray constant (Γ), which accounts for its unique gamma emissions. The total unshielded dose at 1 cm is then scaled by the square of the distance (r, in cm) and multiplied by a shielding factor (μshield). This calculation provides a 'worst-case' or 'maximum risk' estimate because it assumes the sample is a point source and entirely neglects any self-shielding where radiation is absorbed within the mineral itself, meaning actual doses will typically be lower. The resulting dose rate (D) is expressed in microsieverts per hour (μSv/h).

D = ((AU × ΓU) + (ATh × ΓTh) + (AK × ΓK)) / r2 × μshield

Other InformationHide

Notes:
Soluble in water and in acids.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for AphthitaliteHide

References for AphthitaliteHide

Reference List:

Localities for AphthitaliteHide

Showing 117 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the Image symbol to view information about a locality. The Image symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

Image - This locality has map coordinates listed. Image - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. Image - Good crystals or important locality for species. Image - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Australia
 
  • Western Australia
    • Dundas Shire
      • Cocklebiddy Roadhouse
Caves: processes +1 other reference
      • Madura Roadhouse
Bridge (1977)
    • Laverton Shire
      • Lake Rason
Bridge (1973)
Austria
 
  • Tyrol
    • Innsbruck-Land District
      • Absam
        • Hall valley
Spötl (1989) +1 other reference
Bolivia
 
  • Potosí
    • Nor Lípez Province
Bentz (2017)
    • Sud Lípez Province
Bentz (2017)
Canada
 
  • Northwest Territories
    • Lac de Gras
      • Ekati Mine
Kamenetsky et al. (2013)
Chile
 
  • Antofagasta
    • Antofagasta Province
      • Mejillones
        • Mejillones peninsula
SEM-EDS by Joy Desor
  • Tarapacá
    • Iquique Province
      • Iquique
        • Chanabaya
SEM-EDS
China
 
  • Hubei
    • Wuhan
      • Jianghan District
        • Jianghan plain salt deposits
Mineralogical Society of America - ...
  • Inner Mongolia
    • Alxa League (Alashan Prefecture)
      • Alxa Left Banner (Alashan Zuoqi)
Zhenmi Liu (2000)
  • Tibet
    • Nagqu
      • Baingoin Co. (Bange Co.)
Yuanyi Zhao et al. (2004)
      • Nyima Co. (Nima Co.)
Qian Wu et al. (2013)
Xifang Liu and Mianping Zheng (2010)
Xiyu Zheng and Shengsong Yu (1981) +1 other reference
Shaoxiu (1991)
      • Shuanghu Co.
Yuanyi Zhao (2003)
    • Ngari
      • Gê'gyai Co. (Geji Co.)
Shaoxiu (1991) +1 other reference
Shaoxiu (1991)
    • Xigazê Prefecture (Rikaze Prefecture; Shigatse Prefecture)
      • Zhongba Co.
Shaoxiu (1991) +1 other reference
DR Congo
 
  • North Kivu
    • Nyiragongo Territory
Bailey (1980)
El Salvador
 
  • Sonsonate Department
Stoiber et al. (1974)
France
 
  • Hauts-de-France
    • Pas-de-Calais
      • Lens
Naze-Nancy Masalehdani et al. (2009)
  • Réunion
Vlastélic et al. (2013)
Germany
 
  • Hesse
    • Kassel Region
      • Fulda
        • Neuhof
Krah et al. (1988)
      • Hersfeld-Rotenburg
        • Heringen
Weiß (1990)
        • Phillippsthal
Weiß (1990)
  • Lower Saxony
    • Celle District
      • Wathlingen
Weiß (1990)
    • Hanover Region
      • Uetze
        • Hänigsen
Bode "Mineralien und Fundstellen BRD" ...
  • Rhineland-Palatinate
    • Südwestpfalz
      • Hauenstein
        • Wilgartswiesen
Frenzel (1964)
  • Saxony-Anhalt
    • Salzlandkreis
      • Börde-Hakel
        • Westeregeln
Naumann +1 other reference
      • Staßfurt
Palache et al. (1951)
  • Thuringia
    • Wartburg District
      • Krayenberggemeinde
W.I. Borrisenkow (1968)
Iceland
 
  • Southern Region
    • Rangárþing eystra
Balić-Žunić et al. (2016)
Balić-Žunić et al. (2024)
    • Vestmannaeyjar
      • Vestmannaeyjar archipelago (Westman islands)
        • Heimaey Island
Mitolo et al. (2008)
        • Surtsey Island
Jakobsson et al. (1992)
JAKOBSSON et al. (1986) +1 other reference
Indonesia
 
Mineralogical Society of America - ...
  • Special Region of Yogyakarta
Symonds (1993)
Iran
 
  • Qom Province
Lavinsky (n.d.)
Mineralogical Society of America - ...
  • Zanjan Province
    • Dandy to Mahneshan road
Philip Simmons (http://www.mindat.org/mesg-7-237193.html)
Italy
 
  • Campania
    • Metropolitan City of Naples
      • Ercolano
Smithson (1813) +3 other references
      • Pozzuoli
Russo et al. (2017)
Pelloux (1927) +3 other references
Pellino et al. (2025)
  • Lazio
    • Metropolitan City of Rome Capital
      • Cesano geothermal field
Cavarretta et al. (1981) +1 other reference
  • Sicily
    • Agrigento Province
      • Racalmuto
        • Racalmuto saliferous deposit
Barresi G. (1857) +6 other references
      • Realmonte
        • Contrada Scavuzzo
Sergio Russo Collection
    • Caltanissetta Province
      • San Cataldo (San Cattaldo)
        • San Cataldo potash mine
Brescia et al. (2025)
    • Metropolitan City of Catania
      • Etna Volcanic Complex
Palache et al. (1951) +1 other reference
  • Tuscany
    • Grosseto Province
      • Massa Marittima
Dill (1979)
  • Veneto
    • Metropolitan City of Venice
      • Venice
De Vecchi et al. (pp. 417-443)
Japan
 
  • Hokkaidō Prefecture
    • Iburi Subprefecture
      • Usu District
Oana (1962) +1 other reference
  • Kagoshima Prefecture
    • Kagoshima District
      • Mishima village
        • Satsuma-Ioujima (Satsuma-Iwojima; Iou island)
          • Iodake (Iwodake; Ioudake)
Amir Akhavan Collection
Kazakhstan
 
  • Atyrau Region
    • Inder District
Pekov et al. (1993)
Tony Nikischer specimen
Kenya
 
  • Trans-Nzoia County
    • Mount Elgon
Bowell et al. (1996)
Mexico
 
  • Jalisco
    • Colima volcanic complex
Taran et al. (2000)
  • Michoacan
    • Uruapan Municipality
Mineralogical Society of America - ...
Namibia
 
  • Kunene Region
    • Opuwo Rural
Martini et al. (1999)
Nicaragua
 
  • León Department
Stoiber et al. (1974)
Niger
 
  • Agadez
Saidou et al. (2015)
    • Bilma
Saidou et al. (2015)
Saidou et al. (2015)
Saidou et al. (2015)
North Macedonia
 
  • Kavadarci Municipality
    • Vozarci
Đorđević et al. (2024)
Norway
 
  • Buskerud
    • Kongsberg
Hansteen et al. (1994)
Peru
 
  • Arequipa
    • Caylloma Province
Tyc et al. (2022)
  • La Libertad
    • Virù Province
[var: Ammonium-Aphthitalite] Palache et al. (1951)
Russia
 
  • Arkhangelsk Oblast
    • Zimny Bereg District
      • Zimny Bereg kimberlite field
        • Verkhotina occurrence
Golovin et al. (2023)
  • Kamchatka Krai
    • Milkovsky District
      • Tolbachik Volcanic field
Pekov (1998)
found in volcanic fumaroles of the ...
          • Northern Breakthrough (North Breach)
            • Second scoria cone
Pekov et al. (2014) +6 other references
Zelenski et al. (2012)
        • Plosky Tolbachik Volcano
Sharygin et al. (2018)
Shablinskii et al. (2022)
    • Yelizovsky District
      • Mutnovskoe
www.kscnet.ru (2019)
  • Sakha
    • Aldan
      • Inagli Massif
Naumov et al. (2008)
    • Mirninsky District
      • Daldyn
kimberlites of Udachnaya-East pipe (Siberia) +4 other references
Golovin (2025)
    • Oymyakonsky District
Litasov et al. (2017)
    • Upper Muna kimberlite field (Verkhne-Munskoe; Verkhnemunsky)
Sharygin et al. (2021)
  • Sakhalin Oblast
    • Kuril Islands
      • Kurilsky District
        • Iturup Island
Ganino et al. (2019)
      • Severo-Kurilsky District
        • Atlasov Island
          • Alaid volcano
Vergasova et al. (1977) +1 other reference
Saudi Arabia
 
  • Mecca Region
Saudi Geological Survey Open-File ... +1 other reference
South Africa
 
  • Free State
    • Thabo Mofutsanyane District Municipality
      • Setsoto Local Municipality
        • Clocolan
Kamenetsky et al. (2014)
  • Northern Cape
    • Frances Baard District Municipality
      • Sol Plaatje Local Municipality
        • Kimberley
          • KEM JV Mine (Kimberley Ekapa Mining Joint Venture mine; Kimberley Underground mine)
Giuliani et al. (2012) +2 other references
Spain
 
  • Aragon
    • Huesca
      • Sariñena
Vizcayno et al. (1995)
  • Canary Islands
    • Santa Cruz de Tenerife Province
      • La Palma
        • Cumbre Vieja Area
Pérez-López et al. (2025)
  • Valencian Community
    • Alicante
      • Aspe
Benavente +2 other references
      • Orihuela
Benavente et al. (2018, September)
Sweden
 
  • Västernorrland County
    • Sundsvall
Kresten (1990)
Tanzania
 
  • Arusha region
    • Ngorongoro District
Mitchell (2006)
Uganda
 
  • Western Region
    • Kasese
      • Katwe-Kikorongo volcanic field (Katwe volcanic field)
Kasedde et al. (2014)
UK
 
  • England
    • North Yorkshire
      • Redcar and Cleveland
        • Loftus
Mineralogical Society of America - ...
      • Stockton-on-Tees
        • Billingham
Mineralogical Magazine 1959 32 : ...
Ukraine
 
  • Ivano-Frankivsk Oblast
Palache et al. (1951)
  • Lviv Oblast
    • Drohobych Raion
      • Drohobych
Palache et al. (1951)
United Arab Emirates
 
  • Emirate of Fujairah
Audra et al. (2017)
USA
 
  • Alaska
    • Kenai Peninsula Borough
      • Redoubt Mining District
Mineralogical Society of America - ...
  • Arizona
    • Maricopa County
      • Painted Rock Mountains
        • Painted Rock Mining District
          • Theba
Kampf et al. (2019)
Kampf et al. (2025)
  • California
    • Inyo County
      • Deep Springs Valley
Jones (1961) +4 other references
    • San Bernardino County
Palache et al. (1951) +3 other references
Foshag (1920c) +2 other references
  • Hawaii
    • Hawaii County
      • Kau Desert
Washington et al. (1921)
Palache et al. (1951)
Hon et al. (2009)
  • Nevada
    • Esmeralda County
Albemarle Corporation
  • New Mexico
Palache et al. (1951)
    • Eddy County
Philip Simmons (http://www.mindat.org/mesg-7-237193.html) +6 other references
Northrop et al. (1996)
Philip (2013)
 
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To cite: Ralph, J., Von Bargen, D., Martynov, P., Zhang, J., Que, X., Prabhu, A., Morrison, S. M., Li, W., Chen, W., & Ma, X. (2025). Mindat.org: The open access mineralogy database to accelerate data-intensive geoscience research. American Mineralogist, 110(6), 833–844. doi:10.2138/am-2024-9486.
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